Chemist Receives NSF Grant To Enhance Biofuel Technology

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University of Massachusetts Amherst Computational Chemist Scott Auerbach has been awarded a three-year, $330,000 grant from the National Science Foundation to improve basic understanding and optimize the process of producing fuels such as gasoline from plant biomass instead of from petroleum.

For more than 50 years, Auerbach explains, chemists and chemical engineers have refined crude oil using synthetic catalysts inspired by minerals known as zeolites. Zeolites feature uniform arrays of tiny, molecule-sized pores with the right size and shape to convert the hydrocarbon molecules that make up petroleum into high-octane gasoline. Auerbach and others who study zeolites across the globe are asking whether zeolites may also be used to convert plant biomass such as cellulose into gasoline.

He is interested in converting biomass to biofuels for two reasons. First, because plant biomass is renewable via fuel crops, while petroleum requires much more time to make and second, the growth of fuel crops removes carbon dioxide from the atmosphere, providing a "carbon neutral" process for making and using liquid transportation fuels. In contrast, he notes, our present petroleum-based energy economy is "carbon positive" because burning petroleum-based fuels adds carbon dioxide to the atmosphere.

Despite the promise of a biofuel-based energy economy, Auerbach says that "we still haven't perfected the process of making biofuels, which makes today's biofuels too expensive for broad market adoption. That's why we need more research into shape-selective catalysis in zeolites."

The challenge in applying zeolites to make biofuels, he says, is that biomass is generally made of carbohydrates, sugars such as glucose and starches such as cellulose, and these react very differently within the pores of zeolites. Auerbach plans to apply computational chemistry, using computers to reveal the microscopic structures and motions of molecules, to understand how carbohydrates react in zeolite pores. "Computational chemistry provides the most powerful microscope known to humanity, revealing the atomic dance of making fuels," he says. 

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